Bio-inspired multiscale design for perovskite solar cells

Bio-inspired multiscale design for perovskite solar cells

  • Jiang, Q. & Zhu, K. Rapid advances enabling high-performance inverted perovskite solar cells. Nat. Rev. Mater. 9, 399–419 (2024).

    CAS 

    Google Scholar 

  • Kojima, A., Teshima, K., Shirai, Y. & Miyasaka, T. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J. Am. Chem. Soc. 131, 6050–6051 (2009).

    CAS 

    Google Scholar 

  • Chen, H. et al. Improved charge extraction in inverted perovskite solar cells with dual-site-binding ligands. Science 384, 189–193 (2024).

    CAS 

    Google Scholar 

  • Best research-cell efficiency chart. NREL (2025).

  • Saga, T. Advances in crystalline silicon solar cell technology for industrial mass production. npg Asia Mater. 2, 96–102 (2010).

    Google Scholar 

  • Yan, B. et al. 3D laminar flow–assisted crystallization of perovskites for square meter-sized solar modules. Science 388, eadt5001 (2025).

    CAS 

    Google Scholar 

  • Meng, X. et al. Crystallization kinetics modulation of FASnI3 films with pre-nucleation clusters for efficient lead-free perovskite solar cells. Angew. Chem. Int. Ed. 60, 3693–3698 (2021).

    CAS 

    Google Scholar 

  • Song, Y.-H. et al. Planar defect–free pure red perovskite light-emitting diodes via metastable phase crystallization. Sci. Adv. 8, eabq2321 (2022).

    CAS 

    Google Scholar 

  • Zhou, Y., Game, O. S., Pang, S. & Padture, N. P. Microstructures of organometal trihalide perovskites for solar cells: their evolution from solutions and characterization. J. Phys. Chem. Lett. 6, 4827–4839 (2015).

    CAS 

    Google Scholar 

  • Zhou, Y. & Padture, N. P. Gas-induced formation/transformation of organic–inorganic halide perovskites. ACS Energy Lett. 2, 2166–2176 (2017).

    CAS 

    Google Scholar 

  • You, S. et al. Radical polymeric p-doping and grain modulation for stable, efficient perovskite solar modules. Science 379, 288–294 (2023).

    CAS 

    Google Scholar 

  • Hao, M. et al. Flattening grain-boundary grooves for perovskite solar cells with high optomechanical reliability. Adv. Mater. 35, 2211155 (2023).

    CAS 

    Google Scholar 

  • Zhou, Y., Herz, L. M., Jen, A. K.-Y. & Saliba, M. Advances and challenges in understanding the microscopic structure–property–performance relationship in perovskite solar cells. Nat. Energy 7, 794–807 (2022).

    CAS 

    Google Scholar 

  • Xiao, T. et al. Elimination of grain surface concavities for improved perovskite thin-film interfaces. Nat. Energy 9, 999–1010 (2024).

    CAS 

    Google Scholar 

  • Dong, B. et al. Self-assembled bilayer for perovskite solar cells with improved tolerance against thermal stresses. Nat. Energy 10, 342–353 (2025).

    CAS 

    Google Scholar 

  • Fan, J. D. et al. Thermodynamically self-healing 1D–3D hybrid perovskite solar cells. Adv. Energy Mater. 8, 1703421 (2018).

    Google Scholar 

  • Jiang, Y. et al. Reduction of lead leakage from damaged lead halide perovskite solar modules using self-healing polymer-based encapsulation. Nat. Energy 4, 585–593 (2019).

    CAS 

    Google Scholar 

  • Elices, M. (ed.) Structural Biological Materials: Design and Structure–Property Relationships (Pergamon, 2000).

  • Ganewatta, M. S., Wang, Z. & Tang, C. Chemical syntheses of bioinspired and biomimetic polymers toward biobased materials. Nat. Rev. Chem. 5, 753–772 (2021).

    CAS 

    Google Scholar 

  • Gomes, B. S., Simões, B. & Mendes, P. M. The increasing dynamic, functional complexity of bio-interface materials. Nat. Rev. Chem. 2, 0120 (2018).

    Google Scholar 

  • Li, T. et al. Developing fibrillated cellulose as a sustainable technological material. Nature 590, 47–56 (2021).

    CAS 

    Google Scholar 

  • Zhang, Y. et al. Improved fatigue behaviour of perovskite solar cells with an interfacial starch–polyiodide buffer layer. Nat. Photon. 17, 1066–1073 (2023).

    CAS 

    Google Scholar 

  • Burgert, I. Exploring the micromechanical design of plant cell walls. Am. J. Bot. 93, 1391–1401 (2006).

    Google Scholar 

  • Duan, T. et al. Chiral-structured heterointerfaces enable durable perovskite solar cells. Science 384, 878–884 (2024).

    CAS 

    Google Scholar 

  • Qian, X. et al. Bio-inspired pangolin design for self-healable flexible perovskite light-emitting diodes. ACS Nano 16, 17973–17981 (2022).

    CAS 

    Google Scholar 

  • Daghigh Shirazi, H. et al. Bio-inspired surface structures promote optical transmittance and hydrophobicity in cellulose-based films for self-cleaning perovskite solar cells. Commun. Mater. 5, 88 (2024).

    CAS 

    Google Scholar 

  • Huang, G., Xu, J. & Markides, C. N. High-efficiency bio-inspired hybrid multi-generation photovoltaic leaf. Nat. Commun. 14, 3344 (2023).

    CAS 

    Google Scholar 

  • Vasilopoulou, M. et al. Photonic nanostructures mimicking floral epidermis for perovskite solar cells. Cell Rep. Phys. Sci. 3, 101019 (2022).

    CAS 

    Google Scholar 

  • Wang, R. et al. Constructive molecular configurations for surface-defect passivation of perovskite photovoltaics. Science 366, 1509–1513 (2019).

    CAS 

    Google Scholar 

  • Wu, H. et al. Down-selection of biomolecules to assemble “reverse micelle” with perovskites. Nat. Commun. 15, 772 (2024).

    CAS 

    Google Scholar 

  • Watson, B. L., Rolston, N., Printz, A. D. & Dauskardt, R. H. Scaffold-reinforced perovskite compound solar cells. Energy Environ. Sci. 10, 2500–2508 (2017).

    CAS 

    Google Scholar 

  • Li, Z. et al. Boosting mechanical durability under high humidity by bioinspired multisite polymer for high-efficiency flexible perovskite solar cells. Nat. Commun. 16, 1771 (2025).

    CAS 

    Google Scholar 

  • Pei, F. et al. Thermal management enables more efficient and stable perovskite solar cells. ACS Energy Lett. 6, 3029–3036 (2021).

    CAS 

    Google Scholar 

  • Kang, S. M., Ahn, N., Lee, J.-W., Choi, M. & Park, N.-G. Water-repellent perovskite solar cell. J. Mater. Chem. A 2, 20017–20021 (2014).

    CAS 

    Google Scholar 

  • Bhandari, S., Roy, A., Ali, M. S., Mallick, T. K. & Sundaram, S. Cotton soot derived carbon nanoparticles for NiO supported processing temperature tuned ambient perovskite solar cells. Sci. Rep. 11, 23388 (2021).

    CAS 

    Google Scholar 

  • Gil-Escrig, L. et al. Fully vacuum-processed perovskite solar cells on pyramidal microtextures. Sol. RRL 5, 2000553 (2021).

    CAS 

    Google Scholar 

  • Jeong, B. et al. Solvent-assisted gel printing for micropatterning thin organic–inorganic hybrid perovskite films. ACS Nano 10, 9026–9035 (2016).

    CAS 

    Google Scholar 

  • Liu, C. et al. Cellulose-based oxygen-rich activated carbon for printable mesoscopic perovskite solar cells. Sol. RRL 5, 2100333 (2021).

    CAS 

    Google Scholar 

  • Wu, Z. et al. Natural amino acid enables scalable fabrication of high-performance flexible perovskite solar cells and modules with areas over 300 cm2. Small Meth. 6, 2200669 (2022).

    CAS 

    Google Scholar 

  • Geng, Q. et al. Interface engineering via amino acid for efficient and stable perovskite solar cells. Adv. Mater. Interf. 9, 2201641 (2022).

    CAS 

    Google Scholar 

  • Lang, A. et al. Bioinspired molecular bridging in a hybrid perovskite leads to enhanced stability and tunable properties. Adv. Funct. Mater. 30, 2005136 (2020).

    CAS 

    Google Scholar 

  • Bisconti, F. et al. Mimicking natural antioxidant systems for improved photostability in wide-band-gap perovskite solar cells. ACS Nano 18, 1573–1581 (2024).

    CAS 

    Google Scholar 

  • Du, S. et al. Inhibiting perovskite decomposition by a creeper-inspired strategy enables efficient and stable perovskite solar cells. Nat. Commun. 15, 5223 (2024).

    CAS 

    Google Scholar 

  • Li, Y. et al. Plant‐derived l‐theanine for ultraviolet/ozone resistant perovskite photovoltaics. Adv. Energy Mater. 13, 2203190 (2023).

    CAS 

    Google Scholar 

  • Zhang, W. et al. Unveiling the effect of amino acids on the crystallization pathways of methylammonium lead iodide perovskites. J. Energy Chem. 69, 253–260 (2022).

    CAS 

    Google Scholar 

  • Chen, Y. et al. Heterocyclic amino acid molecule as a multifunctional interfacial bridge for improving the efficiency and stability of quadruple cation perovskite solar cells. Nano Energy 107, 108154 (2023).

    CAS 

    Google Scholar 

  • Kim, J.-H. et al. Simultaneously passivating cation and anion defects in metal halide perovskite solar cells using a zwitterionic amino acid additive. Small 17, 2005608 (2021).

    CAS 

    Google Scholar 

  • Xu, P. et al. Manipulating halide perovskite passivation by controlling amino acid derivative isoelectric point for stable and efficient inverted perovskite solar cells. Sol. RRL 7, 2200858 (2023).

    CAS 

    Google Scholar 

  • Jancik Prochazkova, A. et al. Cyclic peptide stabilized lead halide perovskite nanoparticles. Sci. Rep. 9, 12966 (2019).

    Google Scholar 

  • Li, M. et al. Improving the efficiency and stability of MAPbI3 perovskite solar cells by dipeptide molecules. Small 20, 2311400 (2024).

    CAS 

    Google Scholar 

  • Flavell, T. et al. Toward water-resistant, tunable perovskite absorbers using peptide hydrogel additives. ACS Appl. Energy Mater. 7, 8376–8390 (2024).

    CAS 

    Google Scholar 

  • Chen, H.-C., Hung, C.-M. & Kuo, C.-H. Synergistic engineering of natural carnitine molecules allowing for efficient and stable inverted perovskite solar cells. ACS Appl. Mater. Interf. 13, 8595–8605 (2021).

    CAS 

    Google Scholar 

  • Liu, B. et al. Vitamin natural molecule enabled highly efficient and stable planar n–p homojunction perovskite solar cells with efficiency exceeding 24.2%. Adv. Energy Mater. 13, 2203352 (2023).

    CAS 

    Google Scholar 

  • Liu, Q. et al. Heterogeneous lead iodide obtains perovskite solar cells with efficiency of 24.27%. Chem. Eng. J. 448, 137676 (2022).

    CAS 

    Google Scholar 

  • Yang, L. et al. 25.24%‐efficiency FACsPbI3 perovskite solar cells enabled by intermolecular esterification reaction of dl‐carnitine hydrochloride. Adv. Mater. 35, 2211545 (2023).

    CAS 

    Google Scholar 

  • Wang, R. et al. Caffeine improves the performance and thermal stability of perovskite solar cells. Joule 3, 1464–1477 (2019).

    CAS 

    Google Scholar 

  • Xiong, S. et al. Direct observation on p- to n-type transformation of perovskite surface region during defect passivation driving high photovoltaic efficiency. Joule 5, 467–480 (2021).

    CAS 

    Google Scholar 

  • Wu, Z. et al. The tricyclic alkaloid catalyzed crystallization of α-FAPbI3 for high performance antisolvent-free perovskite solar cells. Energy Environ. Sci. 17, 4670–4680 (2024).

    CAS 

    Google Scholar 

  • Deng, Y. et al. Surfactant-controlled ink drying enables high-speed deposition of perovskite films for efficient photovoltaic modules. Nat. Energy 3, 560–566 (2018).

    CAS 

    Google Scholar 

  • Morad, V. et al. Designer phospholipid capping ligands for soft metal halide nanocrystals. Nature 626, 542–548 (2024).

    CAS 

    Google Scholar 

  • Hou, Y. et al. Self-assembly of 0D/3D perovskite bi-layer from a micro-emulsion ink. Adv. Energy Mater. 13, 2300570 (2023).

    CAS 

    Google Scholar 

  • Jin, B. et al. Silk fibroin induced homeotropic alignment of perovskite crystals toward high efficiency and stability. Nano Energy 94, 106936 (2022).

    CAS 

    Google Scholar 

  • Li, K. et al. Au nanocluster assisted microstructural reconstruction for buried interface healing for enhanced perovskite solar cell performance. Adv. Mater. 36, 2310651 (2024).

    CAS 

    Google Scholar 

  • Hou, Y. et al. Enhanced performance and stability in DNA-perovskite heterostructure-based solar cells. ACS Energy Lett. 4, 2646–2655 (2019).

    CAS 

    Google Scholar 

  • Hung, C.-C. et al. Harnessing of spatially confined perovskite nanocrystals using polysaccharide-based block copolymer systems. ACS Appl. Mater. Interf. 14, 30279–30289 (2022).

    CAS 

    Google Scholar 

  • Wang, Y. et al. Manipulating crystal growth and secondary phase PbI2 to enable efficient and stable perovskite solar cells with natural additives. Nano-Micro Lett. 16, 183 (2024).

    Google Scholar 

  • Xiao, B. et al. Enhancing the stability of planar perovskite solar cells by green and inexpensive cellulose acetate butyrate. J. Energy Chem. 76, 259–265 (2023).

    CAS 

    Google Scholar 

  • Han, J. et al. Genetic manipulation of M13 bacteriophage for enhancing the efficiency of virus-inoculated perovskite solar cells with a certified efficiency of 22.3%. Adv. Energy Mater. 11, 2101221 (2021).

    CAS 

    Google Scholar 

  • Lin, H. et al. Denatured M13 bacteriophage‐templated perovskite solar cells exhibiting high efficiency. Adv. Sci. 7, 2000782 (2020).

    CAS 

    Google Scholar 

  • Gao, X. et al. Interfacial modification using the cross-linkable tannic acid for highly-efficient perovskite solar cells with excellent stability. J. Energy Chem. 91, 236–244 (2024).

    CAS 

    Google Scholar 

  • You, S. et al. A biopolymer heparin sodium interlayer anchoring TiO2 and MAPbI3 enhances trap passivation and device stability in perovskite solar cells. Adv. Mater. 30, 1706924 (2018).

    Google Scholar 

  • Xie, L. et al. A deformable additive on defects passivation and phase segregation inhibition enables the efficiency of inverted perovskite solar cells over 24%. Adv. Mater. 35, 2302752 (2023).

    CAS 

    Google Scholar 

  • Xiong, S. et al. Defect-passivation using organic dyes for enhanced efficiency and stability of perovskite solar cells. Sol. RRL 4, 1900529 (2020).

    CAS 

    Google Scholar 

  • Guo, J. et al. Indigo: a natural molecular passivator for efficient perovskite solar cells. Adv. Energy Mater. 12, 2200537 (2022).

    CAS 

    Google Scholar 

  • Hou, Y. et al. Artemisinin (ART)-induced “perovskite/perovskite” bilayer structured photovoltaics. Nano Energy 78, 105133 (2020).

    CAS 

    Google Scholar 

  • Liu, Z. et al. Biomaterial improves the stability of perovskite solar cells by passivating defects and inhibiting ion migration. ACS Appl. Mater. Interf. 16, 31218–31227 (2024).

    CAS 

    Google Scholar 

  • Xiong, S. et al. Defect passivation by nontoxic biomaterial yields 21% efficiency perovskite solar cells. J. Energy Chem. 55, 265–271 (2021).

    CAS 

    Google Scholar 

  • Zhuang, X. et al. Learning from plants: lycopene additive passivation toward efficient and “fresh” perovskite solar cells with oxygen and ultraviolet resistance. Adv. Energy Mater. 12, 2200614 (2022).

    CAS 

    Google Scholar 

  • Zhang, Y. et al. Dopamine-crosslinked TiO2/perovskite layer for efficient and photostable perovskite solar cells under full spectral continuous illumination. Nano Energy 56, 733–740 (2019).

    CAS 

    Google Scholar 

  • Liu, L. et al. Manipulating electron density distribution of nicotinamide derivatives toward defect passivation in perovskite solar cells. Adv. Energy Mater. 13, 2300610 (2023).

    CAS 

    Google Scholar 

  • Xu, X. et al. Ascorbic acid as an effective antioxidant additive to enhance the efficiency and stability of Pb/Sn-based binary perovskite solar cells. Nano Energy 34, 392–398 (2017).

    CAS 

    Google Scholar 

  • Cao, F., Tian, W., Wang, M., Wang, M. & Li, L. Stability enhancement of lead‐free CsSnI3 perovskite photodetector with reductive ascorbic acid additive. InfoMat 2, 577–584 (2020).

    CAS 

    Google Scholar 

  • Dunlap-Shohl, W. A., Zhou, Y., Padture, N. P. & Mitzi, D. B. Synthetic approaches for halide perovskite thin films. Chem. Rev. 119, 3193–3295 (2019).

    CAS 

    Google Scholar 

  • Hamill, J. C. Jr., Schwartz, J. & Loo, Y.-L. Influence of solvent coordination on hybrid organic–inorganic perovskite formation. ACS Energy Lett. 3, 92–97 (2018).

    CAS 

    Google Scholar 

  • Xiang, W. et al. Intermediate phase engineering of halide perovskites for photovoltaics. Joule 6, 315–339 (2022).

    CAS 

    Google Scholar 

  • Wegst, U. G. K., Bai, H., Saiz, E., Tomsia, A. P. & Ritchie, R. O. Bioinspired structural materials. Nat. Mater. 14, 23–36 (2015).

    CAS 

    Google Scholar 

  • De Yoreo, J. J. et al. Crystallization by particle attachment in synthetic, biogenic, and geologic environments. Science 349, aaa6760 (2015).

    Google Scholar 

  • Simpson, T. L. & Volcani, B. E. Silicon and Siliceous Structures in Biological Systems (Springer Science & Business Media, 2012).

  • Athanasiadou, D. & Carneiro, K. M. M. DNA nanostructures as templates for biomineralization. Nat. Rev. Chem. 5, 93–108 (2021).

    CAS 

    Google Scholar 

  • Tavafoghi, M. & Cerruti, M. The role of amino acids in hydroxyapatite mineralization. J. R. Soc. Interf. 13, 20160462 (2016).

    Google Scholar 

  • Levin, A. et al. Biomimetic peptide self-assembly for functional materials. Nat. Rev. Chem. 4, 615–634 (2020).

    CAS 

    Google Scholar 

  • Boyd, C. C., Cheacharoen, R., Leijtens, T. & McGehee, M. D. Understanding degradation mechanisms and improving stability of perovskite photovoltaics. Chem. Rev. 119, 3418–3451 (2019).

    CAS 

    Google Scholar 

  • Huang, J., Tan, S., Lund, P. D. & Zhou, H. Impact of H2O on organic–inorganic hybrid perovskite solar cells. Energy Environ. Sci. 10, 2284–2311 (2017).

    Google Scholar 

  • Frost, J. M. et al. Atomistic origins of high-performance in hybrid halide perovskite solar cells. Nano Lett. 14, 2584–2590 (2014).

    CAS 

    Google Scholar 

  • Leijtens, T., Prasanna, R., Gold-Parker, A., Toney, M. F. & McGehee, M. D. Mechanism of tin oxidation and stabilization by lead substitution in tin halide perovskites. ACS Energy Lett. 2, 2159–2165 (2017).

    CAS 

    Google Scholar 

  • Hidalgo, J. et al. Synergistic role of water and oxygen leads to degradation in formamidinium-based halide perovskites. J. Am. Chem. Soc. 145, 24549–24557 (2023).

    CAS 

    Google Scholar 

  • Liang, J. et al. Origins and influences of metallic lead in perovskite solar cells. Joule 6, 816–833 (2022).

    CAS 

    Google Scholar 

  • Mosconi, E., Meggiolaro, D., Snaith, H. J., Stranks, S. D. & Angelis, F. D. Light-induced annihilation of Frenkel defects in organo-lead halide perovskites. Energy Environ. Sci. 9, 3180–3187 (2016).

    CAS 

    Google Scholar 

  • Kim, G. Y. et al. Large tunable photoeffect on ion conduction in halide perovskites and implications for photodecomposition. Nat. Mater. 17, 445–449 (2018).

    CAS 

    Google Scholar 

  • Aristidou, N. et al. Fast oxygen diffusion and iodide defects mediate oxygen-induced degradation of perovskite solar cells. Nat. Commun. 8, 15218 (2017).

    Google Scholar 

  • Ouyang, Y. et al. Photo-oxidative degradation of methylammonium lead iodide perovskite: mechanism and protection. J. Mater. Chem. A 7, 2275–2282 (2019).

    CAS 

    Google Scholar 

  • Ding, X. et al. Natural antioxidant vitamin C improves photovoltaic performance of tin–lead mixed perovskite solar cells. J. Phys. Chem. Lett. 15, 7214–7220 (2024).

    CAS 

    Google Scholar 

  • Wang, W. et al. Bio-inspired engineering of anti-aging natural cyanidin toward air-stable tin-based perovskite solar cells. ACS Sustain. Chem. Eng. 12, 1019–1028 (2024).

    Google Scholar 

  • Eames, C. et al. Ionic transport in hybrid lead iodide perovskite solar cells. Nat. Commun. 6, 7497 (2015).

    CAS 

    Google Scholar 

  • Ghasemi, M. et al. A multiscale ion diffusion framework sheds light on the diffusion–stability–hysteresis nexus in metal halide perovskites. Nat. Mater. 22, 329–337 (2023).

    CAS 

    Google Scholar 

  • Zhang, L. et al. Crystallization control and multisite passivation of perovskites with amino acid to boost the efficiency and stability of perovskite solar cells. J. Mater. Chem. C 8, 17482–17490 (2020).

    CAS 

    Google Scholar 

  • Zhao, Y. et al. Molecular interaction regulates the performance and longevity of defect passivation for metal halide perovskite solar cells. J. Am. Chem. Soc. 142, 20071–20079 (2020).

    CAS 

    Google Scholar 

  • Wang, K. et al. Melanin–perovskite composites for photothermal conversion. Adv. Energy Mater. 9, 1901753 (2019).

    CAS 

    Google Scholar 

  • Domanski, K. et al. Migration of cations induces reversible performance losses over day/night cycling in perovskite solar cells. Energy Environ. Sci. 10, 604–613 (2017).

    CAS 

    Google Scholar 

  • Yadavalli, S. K., Dai, Z., Zhou, H., Zhou, Y. & Padture, N. P. Facile healing of cracks in organic–inorganic halide perovskite thin films. Acta Mater. 187, 112–121 (2020).

    CAS 

    Google Scholar 

  • Jeong, K., Byeon, J., Jang, J., Ahn, N. & Choi, M. Pulsatile therapy for perovskite solar cells. Joule 6, 1087–1102 (2022).

    CAS 

    Google Scholar 

  • Bischak, C. G. et al. Origin of reversible photoinduced phase separation in hybrid perovskites. Nano Lett. 17, 1028–1033 (2017).

    CAS 

    Google Scholar 

  • Nie, W. et al. Light-activated photocurrent degradation and self-healing in perovskite solar cells. Nat. Commun. 7, 11574 (2016).

    CAS 

    Google Scholar 

  • Ono, L. K., Liu, S. F. & Qi, Y. Reducing detrimental defects for high-performance metal halide perovskite solar cells. Angew. Chem. Int. Ed. 59, 6676–6698 (2020).

    CAS 

    Google Scholar 

  • Hoke, E. T. et al. Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics. Chem. Sci. 6, 613–617 (2014).

    Google Scholar 

  • Gottesman, R. et al. Photoinduced reversible structural transformations in free-standing CH3NH3PbI3 perovskite films. J. Phys. Chem. Lett. 6, 2332–2338 (2015).

    CAS 

    Google Scholar 

  • Huang, K. et al. Manipulating the migration of iodine ions via reverse-biasing for boosting photovoltaic performance of perovskite solar cells. Adv. Sci. 9, 2204163 (2022).

    CAS 

    Google Scholar 

  • Liu, H. et al. Reversible phase transition for durable formamidinium-dominated perovskite photovoltaics. Adv. Mater. 34, 2204458 (2022).

    CAS 

    Google Scholar 

  • Bag, M. et al. Kinetics of ion transport in perovskite active layers and its implications for active layer stability. J. Am. Chem. Soc. 137, 13130–13137 (2015).

    CAS 

    Google Scholar 

  • Tang, S. K. Y. & Marshall, W. F. Self-repairing cells: how single cells heal membrane ruptures and restore lost structures. Science 356, 1022–1025 (2017).

    CAS 

    Google Scholar 

  • Delebecq, E., Pascault, J.-P., Boutevin, B. & Ganachaud, F. On the versatility of urethane/urea bonds: reversibility, blocked isocyanate, and non-isocyanate polyurethane. Chem. Rev. 113, 80–118 (2013).

    CAS 

    Google Scholar 

  • Nam, J. et al. Decoding polymeric additive‐driven self‐healing processes in perovskite solar cells from chemical and physical bonding perspectives. Adv. Energy Mater. 14, 2304062 (2024).

    CAS 

    Google Scholar 

  • Canadell, J., Goossens, H. & Klumperman, B. Self-healing materials based on disulfide links. Macromolecules 44, 2536–2541 (2011).

    CAS 

    Google Scholar 

  • Qiaoyu, Z. et al. Thermal-triggered dynamic disulfide bond self-heals inorganic perovski te solar cells. Angew. Chem. 134, e202116632 (2021).

    Google Scholar 

  • Han, T.-H. et al. Perovskite–polymer composite cross-linker approach for highly-stable and efficient perovskite solar cells. Nat. Commun. 10, 520 (2019).

    CAS 

    Google Scholar 

  • Meng, X. et al. Stretchable perovskite solar cells with recoverable performance. Angew. Chem. Int. Ed. 59, 16602–16608 (2020).

    CAS 

    Google Scholar 

  • Yang, Z. et al. Supramolecular polyurethane “ligaments” enabling room-temperature self-healing flexible perovskite solar cells and mini-modules. Small 20, 2307186 (2024).

    CAS 

    Google Scholar 

  • Lan, Y. et al. Thermally driven self-healing efficient flexible perovskite solar cells. Nano Energy 100, 107523 (2022).

    CAS 

    Google Scholar 

  • Peng, X. et al. Dynamic covalent polymer engineering for stable and self-healing perov skite solar cells. Mater. Horiz. 10, 5223–5234 (2023).

    Google Scholar 

  • Chen, Z. et al. Perovskite grain-boundary manipulation using room-temperature dynamic self-healing “ligaments” for developing highly stable flexible perovskite solar cells with 23.8% efficiency. Adv. Mater. 35, 2300513 (2023).

    CAS 

    Google Scholar 

  • Li, G., Li, S., Ahmed, J., Tian, W. & Li, L. Flexible perovskite photodetector with room-temperature self-healing capability without external trigger. InfoMat 6, e12594 (2024).

    CAS 

    Google Scholar 

  • Yang, J. et al. Synergistic toughening and self-healing strategy for highly efficient and stable flexible perovskite solar cells. Adv. Funct. Mater. 33, 2214984 (2023).

    CAS 

    Google Scholar 

  • Zhang, K. et al. Interface chelation induced by pyridine-based polymer for efficient and durable air-processed perovskite solar cells. Angew. Chem. 134, e202112673 (2022).

    Google Scholar 

  • Zhao, Y. et al. A polymer scaffold for self-healing perovskite solar cells. Nat. Commun. 7, 10228 (2016).

    CAS 

    Google Scholar 

  • Son, D.-Y. et al. Self-formed grain boundary healing layer for highly efficient CH3NH3PbI3 perovskite solar cells. Nat. Energy 1, 1–8 (2016).

    Google Scholar 

  • Zhou, Z. et al. Methylamine-gas-induced defect-healing behavior of CH3NH3PbI3 thin films for perovskite solar cells. Angew. Chem. Int. Ed. 54, 9705–9709 (2015).

    CAS 

    Google Scholar 

  • Li, Z. et al. Ammonia for post-healing of formamidinium-based perovskite films. Nat. Commun. 13, 4417 (2022).

    CAS 

    Google Scholar 

  • Yang, Z. et al. Self-healing and efficient flexible perovskite solar cells enabled by host–guest interaction and a 2D/3D heterostructure. J. Mater. Chem. A 10, 22445–22452 (2022).

    CAS 

    Google Scholar 

  • Zhang, H. et al. Multimodal host–guest complexation for efficient and stable perovskite photovoltaics. Nat. Commun. 12, 3383 (2021).

    CAS 

    Google Scholar 

  • Xue, T. et al. Self-healing ion-conducting elastomer towards record efficient flexible perovskite solar cells with excellent recoverable mechanical stability. Energy Environ. Sci. 17, 2621–2630 (2024).

    CAS 

    Google Scholar 

  • Zhao, J. et al. Strained hybrid perovskite thin films and their impact on the intrinsic stability of perovskite solar cells. Sci. Adv. 3, eaao5616 (2017).

    Google Scholar 

  • Rolston, N. et al. Mechanical integrity of solution-processed perovskite solar cells. Extreme Mech. Lett. 9, 353–358 (2016).

    Google Scholar 

  • Ramirez, C., Yadavalli, S. K., Garces, H. F., Zhou, Y. & Padture, N. P. Thermo-mechanical behavior of organic-inorganic halide perovskites for solar cells. Scr. Mater. 150, 36–41 (2018).

    CAS 

    Google Scholar 

  • Meng, X. et al. Bio-inspired vertebral design for scalable and flexible perovskite solar cells. Nat. Commun. 11, 3016 (2020).

    CAS 

    Google Scholar 

  • Ma, S. et al. Resist thermal shock through viscoelastic interface encapsulation in perovskite solar cells. Energy Environ. Mater. 7, e12739 (2024).

    CAS 

    Google Scholar 

  • Shen, Y. et al. Enzymatic polymerization of enantiomeric l−3,4-dihydroxyphenylalanine into films with enhanced rigidity and stability. Nat. Commun. 14, 3054 (2023).

    CAS 

    Google Scholar 

  • Li, Z. et al. Hyperbranched polymer functionalized flexible perovskite solar cells with mechanical robustness and reduced lead leakage. Nat. Commun. 14, 6451 (2023).

    CAS 

    Google Scholar 

  • Zhang, X. et al. Unraveling the combined photothermal stability of common perovskite solar cell compositions. ACS Energy Lett. 9, 5728–5736 (2024).

    CAS 

    Google Scholar 

  • Ma, S. et al. Development of encapsulation strategies towards the commercialization of perovskite solar cells. Energy Environ. Sci. 15, 13–55 (2022).

    CAS 

    Google Scholar 

  • Kang, S. M. et al. Moth-eye TiO2 layer for improving light harvesting efficiency in perovskite solar cells. Small 12, 2443–2449 (2016).

    CAS 

    Google Scholar 

  • Zhu, Y. et al. Moth eye‐inspired highly efficient, robust, and neutral‐colored semitransparent perovskite solar cells for building‐integrated photovoltaics. EcoMat 3, e12117 (2021).

    CAS 

    Google Scholar 

  • The light fantastic. Nat. Chem. Biol. 10, 483 (2014).

  • Dawson, T. L. Light-harvesting and light-protecting pigments in simple life forms. Color. Technol. 123, 129–142 (2007).

    CAS 

    Google Scholar 

  • Tavakoli, M. M. et al. Highly efficient flexible perovskite solar cells with antireflection and self-cleaning nanostructures. ACS Nano 9, 10287–10295 (2015).

    CAS 

    Google Scholar 

  • Sun, J. et al. Biomimetic moth-eye nanofabrication: enhanced antireflection with superior self-cleaning characteristic. Sci. Rep. 8, 5438 (2018).

    Google Scholar 

  • Krajewski, M. et al. Roller nanoimprinted honeycomb texture as an efficient antireflective coating for perovskite solar cells. Adv. Mater. Interf. 10, 2300134 (2023).

    CAS 

    Google Scholar 

  • Choi, D. H., Nam, S. K., Jung, K. & Moon, J. H. 2D photonic crystal nanodisk array as electron transport layer for highly efficient perovskite solar cells. Nano Energy 56, 365–372 (2019).

    CAS 

    Google Scholar 

  • Siddique, R. H. et al. Bioinspired phase-separated disordered nanostructures for thin photovoltaic absorbers. Sci. Adv. 3, e1700232 (2017).

    Google Scholar 

  • Zhan, Y. et al. A butterfly-inspired hierarchical light-trapping structure towards a high-performance polarization-sensitive perovskite photodetector. Angew. Chem. 131, 16608–16614 (2019).

    Google Scholar 

  • Chen, D., Li, S., Li, B. & Guo, P. Thermal transport in metal halide perovskites and other third-generation photovoltaic materials. Appl. Phys. Rev. 11, 041311 (2024).

    CAS 

    Google Scholar 

  • Zhao, L. et al. Thermal management enables bright and stable perovskite light-emitting diodes. Adv. Mater. 32, 2000752 (2020).

    CAS 

    Google Scholar 

  • Zhang, H. et al. Biologically inspired flexible photonic films for efficient passive radiative cooling. Proc. Natl Acad. Sci. USA 117, 14657–14666 (2020).

    Google Scholar 

  • Huang, G. et al. Radiative cooling and indoor light management enabled by a transparent and self-cleaning polymer-based metamaterial. Nat. Commun. 15, 3798 (2024).

    CAS 

    Google Scholar 

  • Wang, Y. et al. Encapsulation and stability testing of perovskite solar cells for real life applications. ACS Mater. Au 2, 215–236 (2022).

    CAS 

    Google Scholar 

  • Cheacharoen, R. et al. Design and understanding of encapsulated perovskite solar cells to withstand temperature cycling. Energy Environ. Sci. 11, 144–150 (2018).

    CAS 

    Google Scholar 

  • Mohammadi, M. et al. Encapsulation strategies for highly stable perovskite solar cells under severe stress testing: damp heat, freezing, and outdoor illumination conditions. ACS Appl. Mater. Interf. 13, 45455–45464 (2021).

    CAS 

    Google Scholar 

  • Mariani, P. et al. Low-temperature strain-free encapsulation for perovskite solar cells and modules passing multifaceted accelerated ageing tests. Nat. Commun. 15, 4552 (2024).

    CAS 

    Google Scholar 

  • Wang, T. et al. Room temperature nondestructive encapsulation via self-crosslinked fluorosilicone polymer enables damp heat-stable sustainable perovskite solar cells. Nat. Commun. 14, 1342 (2023).

    CAS 

    Google Scholar 

  • Lemaire, B. et al. Flexible fluid-based encapsulation platform for water-sensitive materials. Proc. Natl Acad. Sci. USA 120, e2308804120 (2023).

    CAS 

    Google Scholar 

  • Barthlott, W. & Neinhuis, C. Purity of the sacred lotus, or escape from contamination in biological surfaces. Planta 202, 1–8 (1997).

    CAS 

    Google Scholar 

  • Si, Y., Dong, Z. & Jiang, L. Bioinspired designs of superhydrophobic and superhydrophilic materials. ACS Cent. Sci. 4, 1102–1112 (2018).

    CAS 

    Google Scholar 

  • Zhan, Y., Peng, J., Cao, C. & Cheng, Q. A biomineralization-inspired strategy of self-encapsulation for perovskite solar cells. Nano Energy 101, 107575 (2022).

    CAS 

    Google Scholar 

  • Li, Z. et al. Synthesis of a lattice-resolved laminate-structured perovskite heterointerface. Nat. Synth. (2025).

    Google Scholar 

  • Parle, E., Dirks, J. H. & Taylor, D. Damage, repair and regeneration in insect cuticle: the story so far, and possibilities for the future. Arthropod Struct. Dev. 46, 49–55 (2017).

    Google Scholar 

  • Emery, Q. et al. Tips and tricks for a good encapsulation for perovskite-based solar cells. Prog. Photovolt. Res. Appl. 33, 551–559 (2025).

    CAS 

    Google Scholar 

  • Zhang, Y. & Zhou, Y. Machine learning quantification of grain characteristics for perovskite solar cells. Matter 7, 255–265 (2024).

    CAS 

    Google Scholar 

  • Zhang, J. et al. Advancing perovskite photovoltaic technology through machine learning-driven automation. InfoMat 7, e70005 (2025).

    CAS 

    Google Scholar 

  • Wang, W.-T. et al. Water- and heat-activated dynamic passivation for perovskite photovoltaics. Nature 632, 294–300 (2024).

    CAS 

    Google Scholar 

  • Shukla, A., Kant, K., Biwole, P. H., Pitchumani, R. & Sharma, A. Melting and solidification of a phase change material with constructal tree-shaped fins for thermal energy storage. J. Energy Storage 53, 105158 (2022).

    Google Scholar 

  • Pitchaiya, S., Eswaramoorthy, N., Madurai Ramakrishnan, V., Natarajan, M. & Velauthapillai, D. Bio-inspired graphitic carbon-based large-area (10 × 10 cm2) perovskite solar cells: stability assessments under indoor, outdoor, and water-soaked conditions. ACS Appl. Mater. Interf. 14, 43050–43066 (2022).

    CAS 

    Google Scholar 

  • Luo, H. et al. Bioinspired “cage traps” for closed-loop lead management of perovskite solar cells under real-world contamination assessment. Nat. Commun. 14, 4730 (2023).

    CAS 

    Google Scholar 

  • Saio, T., Guan, X., Rossi, P., Economou, A. & Kalodimos, C. G. Structural basis for protein antiaggregation activity of the trigger factor chaperone. Science 344, 1250494 (2014).

    Google Scholar 

  • Balchin, D., Hayer-Hartl, M. & Hartl, F. U. In vivo aspects of protein folding and quality control. Science 353, aac4354 (2016).

    Google Scholar 

  • Kamide, K., Okajima, K., Matsui, T. & Manabe, S. Dissolution process and dissolved state of cellulose in dimethylformamide–chloral–pyridine system. Polym. J. 12, 521–534 (1980).

    CAS 

    Google Scholar 

  • Krasnokutski, S. A. et al. Formation of extraterrestrial peptides and their derivatives. Sci. Adv. 10, eadj7179 (2024).

    CAS 

    Google Scholar 

  • Herbig, A. & Renard, C. M. Factors that impact the stability of vitamin C at intermediate temperatures in a food matrix. Food Chem. 220, 444–451 (2017).

    CAS 

    Google Scholar 

  • Hu, Q. et al. In situ dynamic observations of perovskite crystallisation and microstructure evolution intermediated from [PbI6]4− cage nanoparticles. Nat. Commun. 8, 15688 (2017).

    CAS 

    Google Scholar 

  • Pool, V. L. et al. Thermal engineering of FAPbI3 perovskite material via radiative thermal annealing and in situ XRD. Nat. Commun. 8, 14075 (2017).

    CAS 

    Google Scholar 

  • Helgeson, H. C. & Amend, J. P. Relative stabilities of biomolecules at high temperatures and pressures. Thermochim. Acta 245, 89–119 (1994).

    CAS 

    Google Scholar 

  • Choi, S. H. et al. Scalable multistep roll-to-roll printing of multifunctional and robust reentrant microcavity surfaces via a wetting-induced process. Adv. Mater. 37, 2411064 (2024).

    Google Scholar 

  • Yakoob, M. A. et al. Efficiency-enhanced scalable organic photovoltaics using roll-to-roll nanoimprint lithography. ChemSusChem 15, e202101611 (2022).

    CAS 

    Google Scholar 

  • Harwell, J. & Samuel, I. D. W. Nanoimprint lithography as a route to nanoscale back-contact perovskite solar cells. ACS Appl. Nano Mater. 6, 14940–14947 (2023).

    CAS 

    Google Scholar 

  • Henriques, C. A. et al. Cost-efficient method for unsymmetrical meso-aryl porphyrins and iron oxide-porphyrin hybrids prepared thereof. Dalton Trans. 45, 16211–16220 (2016).

    CAS 

    Google Scholar 

  • Gao, L. et al. Several economical and eco-friendly bio-carbon electrodes for highly efficient perovskite solar cells. Carbon 162, 267–272 (2020).

    CAS 

    Google Scholar 

  • Zhu, K. et al. Ultraflexible and lightweight bamboo-derived transparent electrodes for perovskite solar cells. Small 15, 1902878 (2019).

    Google Scholar 

  • Gao, L. et al. Flexible, transparent nanocellulose paper-based perovskite solar cells. npj Flex. Electron. 3, 4 (2019).

    Google Scholar 

  • Islam, A. et al. Biomass-derived materials for interface engineering in organic/perovskite photovoltaic and light-emitting devices. Adv. Mater. Technol. 8, 2201390 (2023).

    CAS 

    Google Scholar 

  • Wang, L. et al. A Eu3+ –Eu2+ ion redox shuttle imparts operational durability to Pb–I perovskite solar cells. Science 363, 265–270 (2019).

    CAS 

    Google Scholar 

  • Ventura, C. et al. On the toxicity of cellulose nanocrystals and nanofibrils in animal and cellular models. Cellulose 27, 5509–5544 (2020).

    CAS 

    Google Scholar 

  • Li, J.-M. et al. Functional differences between l– and d-carnitine in metabolic regulation evaluated using a low-carnitine Nile tilapia model. Br. J. Nutr. 122, 625–638 (2019).

    CAS 

    Google Scholar 

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